As part of the glass manufacturing process, it is inevitable that float glass
may contain some impurities. Such impurities are allowed by standards as long
they are kept below specified requirements of size, intensity and frequency. One
type of such impurities is nickel sulfide (NiS). Nickel is present in items such
as sand, firebrick and machinery while Sulfur is present in items such as fuel
or sodium sulfate, which is one of glass batch's ingredients.
In case of NiS presence, most NiS are stable and their presence is usually
negligibly small. It is however that in certain rare cases, NiS when cooled in
manufacturing process down to room temperature, the NiS would undergo a change
in crystalline structure such that the volume of NiS is increased.
In case of float glass, as the expansion of NiS takes place when glass is at
annealing temperatures, the additional stress due to expansion is eliminated by
relaxation of stress in annealing process.

The
manufacturing process of tempered glass requires quenching, and the rapid
quenching process traps the NiS when its volume is small. Over time, the NiS may
expand in size. When the NiS is located in the center of tension area, the
expansion of NiS is capable to provide stress that is sufficient to break the
tempered glass.
The NiS presence can cause spontaneous breakage in tempered glass even when
no load is being applied, even after a long period have passed since the
fabrication of the tempered glass. The NiS presence is typically small and are
impossible to locate and identify in unbroken glass.
In order to deal with such occurrence, Glass manufacturers implemented batch
quality control programs as well as eliminating of nickel containing materials
in the manufacturing process. The measures implemented are effective to reduce
but not completely eliminate spontaneous breakage caused by nickel sulfide.
It is noted that heat soaking may uncover NiS presence in glass, however, it
is not totally effective as it is unable to detect all of NiS presence, and can
reduce the strength of tempered glass by around 7%.
Though little, the occurrence of spontaneous breakage of tempered glass
cannot be overlooked. For safety reasons, designers and engineers only uses
tempered glass in occasions where spontaneous breakage will not cause harm or
major problems. In areas where added strength of glass is required and tempered
glass is unsuitable to be used, heat-strengthened glass or laminated glass are
used instead.

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